Permanently Microporous Metal-Organic Polyhedra.

Chemical Reviews
Aeri J GosselinEric D Bloch

Abstract

As compared to porous network solids, including metal-organic frameworks, covalent-organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials are relatively unexplored. Additionally, within porous molecular space, porous organic cages (POCs) have been the most widely reported over the past decade. Relatively recently, however, porous hybrid metal-organic molecular complexes have received considerable attention with a large fraction of surface areas for these coordination cages reported over the past three years. This review focuses on advances in this area. We highlight the recent work with permanently microporous metal-organic polyhedra (MOPs). Analogous to early work in the area of MOFs, the vast majority of MOPs for which surface areas have been reported have been based on paddlewheel building units and carboxylate ligands. We describe the synthesis of porous cages and highlight those based on monometallic, bimetallic, trimetallic, tetrametallic, and higher nuclearity clusters. Finally, we showcase work wherein the porosity of MOPs has been leveraged for applications related to the storage and separation of small molecules and the incorporation of these porous and potentially porous cages into m...Continue Reading

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Citations

Nov 20, 2020·Angewandte Chemie·Xiuxiu GuoZhenjie Zhang
Jan 8, 2021·Chemical Communications : Chem Comm·Xin-Ying WangZhong-Min Su
Oct 29, 2020·Chemistry : a European Journal·Meaghan M DeeganEric D Bloch
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May 18, 2021·Chemistry : a European Journal·Ru-Jin LiKay Severin
Jun 15, 2021·Chemical Science·Alexandra M AntonioEric D Bloch
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Nov 17, 2021·Chemical Society Reviews·Yao WangYing-Feng Han
Dec 9, 2021·Journal of the American Chemical Society·Belén Lerma-BerlangaCarlos Martí-Gastaldo
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Feb 2, 2022·Chemical Communications : Chem Comm·Jorge AlbaladDaniel Maspoch
Feb 5, 2022·Advanced Science·Akim Khobotov-BakishevDaniel Maspoch

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