Persulfurated aromatic compounds

Angewandte Chemie
Marc GingrasYoann M Chabre

Abstract

Persulfurated arenes have been known for about 50 years but they were underexploited in chemistry in spite of facile, mild, and high-yielding syntheses. Their properties (redox potentials, UV/Vis absorption, conductivity, nonlinear optical properties, etc.) are mainly due to the aromaticity of the ring with sp2-hybridized carbon atoms and to the electronic contribution from numerous divalent sulfur ligands, which also stabilize negative or positive charges. The characteristic conformational patterns of the sulfur ligands often facilitate preorganization in supramolecular assemblies, with or without thiophilic metal cations, for designing redox sensors, ion-selective membranes, clathrates, organic conductors, nonlinear optical materials, liquid crystals, coordination polymers, and bioinorganic systems. A new class of supramolecules with various molecular shapes such as asterisks, chains, wheels, and windmills were reported.

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Citations

May 18, 2010·Journal of the American Chemical Society·Eric L DaneTimothy M Swager
Sep 25, 2012·The Journal of Organic Chemistry·Dayna L Turner, Thomas P Vaid
Oct 11, 2007·Chemical Communications : Chem Comm·Giacomo BergaminiPier Giorgio Merli
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Feb 21, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Marco VillaPaola Ceroni
Jul 6, 2019·Chemistry : a European Journal·Tobias BlockhausKarlheinz Sünkel
Feb 13, 2013·Chemical Society Reviews·Yoann M Chabre, René Roy
May 1, 2013·Chemical Society Reviews·Marc GingrasRené Roy
Apr 21, 2011·Angewandte Chemie·Rajarshi Samanta, Andrey P Antonchick
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Nov 19, 2019·ACS Omega·Jan Cz Dobrowolski

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