Pesticide fate in cultivated mountain basins: The improved DynAPlus model for predicting peak exposure and directing sustainable monitoring campaigns to protect aquatic ecosystems

Chemosphere
Melissa MorselliAntonio Di Guardo

Abstract

Agricultural activities can involve the use of plant protection products (PPPs) and the use of such chemicals can occur near surface waters bodies, thus creating a potential for adverse effects on aquatic ecosystems. In mountain watersheds, where runoff fluxes are particularly rapid due to side slopes, exposure is generally characterized by short but intense concentration peaks. Monitoring campaigns are often inadequate or too expensive to be carried out and modelling tools are therefore vital for exposure assessment and their use is encouraged by current legislation. However, currently adopted models and scenarios (e.g., FOCUS for PPPs) are often too conservative and/or "static" to accurately capture exposure variability, and the need for more realistic and dynamic tools is now one of the major challenges for risk assessment. In a previous work, the new fate model DynAPlus was developed to improve pesticide fate predictions in cultivated mountain basins and was successfully evaluated against chlorpyrifos water concentrations measured in a mountain stream in Northern Italy. However, the need for some model improvements (e.g., the inclusion of dissolved organic matter and macrophytes in water) was highlighted. In this work, DynA...Continue Reading

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