Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Chemical Communications : Chem Comm
Irene LingColin L Raston

Abstract

We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

References

Oct 17, 1998·Nature·J M GrimesD I Stuart
Oct 14, 2004·Journal of the American Chemical Society·Jerry L AtwoodHelen R Webb
Dec 16, 2004·Angewandte Chemie·Banu KesanliWenbin Lin
Dec 17, 2004·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·D C Rapaport
Mar 16, 2005·Accounts of Chemical Research·Nathan W OckwigOmar M Yaghi
Apr 20, 2005·Accounts of Chemical Research·Gérard FéreyFranck Millange
Apr 28, 2005·Journal of the American Chemical Society·Eun Young LeeMyunghyun Paik Suh
Jun 30, 2005·Journal of the American Chemical Society·Mircea Dinca, Jeffrey R Long
Feb 1, 2007·Chemical Society Reviews·Stephen J Loeb
Jun 7, 2008·Journal of the American Chemical Society·Jenny G VitilloAdriano Zecchina
Jun 11, 2008·Journal of the American Chemical Society·Kristine K TanabeSeth M Cohen
Aug 6, 2008·Nature Reviews. Microbiology·Todd O YeatesJessup M Shively
Jul 23, 2011·Science·Yuzhou LiuMichael D Ward
Mar 9, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Irene LingColin L Raston
Apr 19, 2012·Nature Communications·Sara PasqualeJavier de Mendoza
Jun 2, 2012·Chemistry : a European Journal·Andrew V MossineJerry L Atwood
Jul 28, 2012·Science·Joost de Graaf, Liberato Manna
Jul 28, 2012·Science·Pablo F DamascenoSharon C Glotzer
Oct 17, 2014·Chemical Society Reviews·Nazir AhmadFrancis Verpoort

❮ Previous
Next ❯

Methods Mentioned

BETA
dynamic light scattering
transmission electron microscopy
NMR
small angle neutron scattering
Small-angle neutron scattering
X-ray
SANS

Software Mentioned

CrystalExplorer

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.