Phenanthroline-A Versatile Ligand for Advanced Functional Polymeric Materials

Chemistry : a European Journal
Hannah RothfussChristopher Barner-Kowollik

Abstract

The controlled incorporation of phenanthroline moieties into polymers is introduced, demonstrating their application as metal-ion complexing ligands for the construction of advanced macromolecular structures. Specifically, two phenanthroline-containing monomers based on acrylate and styrene functionalities, were synthesized. Each monomer was readily copolymerized with either N,N-dimethylacrylamide or styrene via nitroxide-mediated polymerization, resulting in narrowly distributed polar or non-polar copolymers. To demonstrate the versatility of the established polymer systems, the polar polymer was employed for transition metal induced single-chain nanoparticle formation, verified by diffusion-ordered NMR and UV/Vis spectroscopy. Furthermore, the non-polar polymer allows facile incorporation of lanthanide ions, creating luminescent metallo-polymers, in-depth characterized by advanced photophysical experiments and 2D NMR measurements.

References

Nov 15, 2005·Chemical Society Reviews·Jean-Claude G Bünzli, Claude Piguet
Jun 24, 2008·Journal of the American Chemical Society·Andrea CannizzoMajed Chergui
Sep 26, 2008·Journal of the American Chemical Society·Yoshihiro YamaguchiZen-Ichi Yoshida
Jul 10, 2009·Chemical Society Reviews·Gianluca AccorsiNicola Armaroli
Dec 8, 2010·Chemical Reviews·Brad M RosenVirgil Percec
Jan 22, 2011·Analytical Chemistry·Knut Rurack, Monika Spieles
Nov 10, 2011·Inorganic Chemistry·Dominique T ThielemannGlen B Deacon
Mar 17, 2012·Angewandte Chemie·Eric A AppelOren A Scherman
Mar 2, 2013·Chemical Society Reviews·Jianzhang ZhaoSong Guo
Aug 10, 2013·Scientific Reports·Nathalia B D LimaAlfredo M Simas
Aug 14, 2015·Chemical Reviews·Sudheendran MavilaN Gabriel Lemcoff
Dec 20, 2016·Chemistry : a European Journal·Yasuchika HasegawaKoji Fushimi
Oct 27, 2017·Nanomaterials·Jon Rubio-CervillaJosé A Pomposo
Feb 20, 2018·Journal of the American Chemical Society·Yiliu LiuAnja R A Palmans
Apr 10, 2018·Journal of the American Chemical Society·Hannah RothfussChristopher Barner-Kowollik
May 5, 2018·Chemical Communications : Chem Comm·Alena S KalyakinaStefan Bräse

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Citations

Jun 11, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Nadine C MichenfelderAndreas-Neil Unterreiner

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