Phosphazene Base tBu-P4 Catalyzed Methoxy-Alkoxy Exchange Reaction on (Hetero)Arenes

Chemistry : a European Journal
Masanori ShigenoYoshinori Kondo

Abstract

The organic superbase tBu-P4 catalyzes methoxy-alkoxy exchange reactions on (hetero)arenes with alcohols. The catalytic reaction proceeded efficiently with electron-deficient methoxy(hetero)arenes as well as with a variety of alcohols, including 3-amino-1-propanol, β-citronellol, menthol, and cholesterol. An intramolecular version of this reaction furnished six- and seven-membered ring compounds.

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Citations

Aug 26, 2020·Chemistry : a European Journal·Thomas R PuleoJeffrey S Bandar
Jan 14, 2021·The Journal of Organic Chemistry·Tatsushi YabutaRyosuke Matsubara
Nov 12, 2020·Organic Letters·Masanori ShigenoYoshinori Kondo
Nov 5, 2020·Journal of the American Chemical Society·Franck Le VaillantJosep Cornella
Jul 3, 2019·Organic Letters·Masanori ShigenoYoshinori Kondo

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