Phosphonium-Based Porous Ionic Polymer with Hydroxyl Groups: A Bifunctional and Robust Catalyst for Cycloaddition of CO2 into Cyclic Carbonates

Polymers
Yizhu LeiZhou Yang

Abstract

The integration of synergic hydrogen bond donors and nucleophilic anions that facilitates the ring-opening of epoxide is an effective way to develop an active catalyst for the cycloaddition of CO2 with epoxides. In this work, a new heterogeneous catalyst for the cycloaddition of epoxides and CO2 into cyclic carbonates based on dual hydroxyls-functionalized polymeric phosphonium bromide (PQPBr-2OH) was presented. Physicochemical characterizations suggested that PQPBr-2OH possessed large surface area, hierarchical pore structure, functional hydroxyl groups, and high density of active sites. Consequently, it behaved as an efficient, recyclable, and metal-free catalyst for the additive and solvent free cycloaddition of epoxides with CO2. Comparing the activity of PQPBr-2OH with that of the reference catalysts based on mono and non-hydroxyl functionalized polymeric phosphonium bromides suggested that hydroxyl functionalities in PQPBr-2OH showed a critical promotion effect on its catalytic activity for CO2 conversion. Moreover, PQPBr-2OH proved to be quite robust and recyclable. It could be reused at least ten times with only a slight decrease of its initial activity.

References

Aug 26, 2014·Chemical Communications : Chem Comm·Qi SunFeng-Shou Xiao
Sep 15, 2015·Chemical Communications : Chem Comm·Jinquan WangYugen Zhang
Oct 13, 2016·Chemical Society Reviews·Jian-Ke SunJiayin Yuan
Feb 15, 2019·Chemical Reviews·Xin LiXiaobo Chen
Aug 14, 2019·Polymers·Norini TahirPascal Van Der Voort

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Methods Mentioned

BETA
transmission electron microscopy
nuclear magnetic resonance

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