Photo-control of the magnetic properties of Dy(III) and Ho(III) homometal coordination polymers bridged by a diarylethene ligand

Dalton Transactions : an International Journal of Inorganic Chemistry
Goulven CosquerMasahiro Yamashita

Abstract

Two-dimensional Dy(III) and Ho(III) homometal coordination polymers containing the photochromic ligand 1,2-bis(5-carboxyl-2-methyl-3-thienyl)perfluorocyclopentene (DTE) with the general formula [Ln2(DTE)3(bipyridine)2(H2O)2]n (Ln = Dy and Ho) were obtained, and the magnetic properties of their open (Dy-o and Ho-o) and closed forms (Dy-c and Ho-c) were investigated. The Dy complexes exhibited slow magnetic relaxation without an external dc field. The magnetic properties of the Dy complexes were irreversibly affected by the conformation of the ligand.

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Citations

Dec 26, 2015·Inorganic Chemistry·Ritwik ModakSanchita Goswami
Mar 31, 2016·Scientific Reports·Ahmed FetohMasahiro Yamashita
Jan 23, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Dan-Ping GongDeng-Ke Cao
Feb 7, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Qian ZouLi-Min Zheng
Sep 5, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Xin-Da HuangLi-Min Zheng
Jan 26, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Bertrand LefeuvreFabrice Pointillart
Oct 16, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Gang HuangKevin Bernot

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