Photocatalytic difunctionalisations of alkenes with N-SCN sulfoximines

Chemical Communications : Chem Comm
Duo ZhangCarsten Bolm

Abstract

Reacting N-Br sulfoximines with ammonium thiocyanate leads to unprecedented sulfur reagents, which add to vinyl arenes under photocatalysis via N-centered sulfoximidoyl radicals. As a result, 1,2-difunctionalised products are obtained, which can subsequently be derivatised taking advantage of the unique properties of the thiocyanate group.

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Citations

Aug 7, 2018·Chemistry : a European Journal·Han WangCarsten Bolm
Jun 26, 2020·Organic & Biomolecular Chemistry·Xiaomin WangQian Zhang
Sep 24, 2020·Organic & Biomolecular Chemistry·Chengkou LiuKai Guo
Aug 21, 2021·Organic Letters·Chenyang WangCarsten Bolm
Jan 11, 2020·The Journal of Organic Chemistry· QumruddeenChandra Bhushan Tripathi
Sep 23, 2021·Organic & Biomolecular Chemistry·Irshad Maajid TailyPrabal Banerjee

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Methods Mentioned

BETA
column chromatography

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