Photochemical transformations of tetrazole derivatives: applications in organic synthesis.

Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry
Luís M T FrijaM L S Cristiano

Abstract

Tetrazoles remain a challenge to photochemists. Photolysis leads to cleavage of the tetrazolyl ring, may involve various photodegradation pathways and may produce a diversity of photoproducts, depending on the structure and conformational flexibility of the substituents and the possibility of tautomerism. If the photochemistry of tetrazoles is considered within the frame of synthetic applications the subject is even more challenging, since the ultimate goal is to achieve selectivity and high yield. In addition, the photoproducts must remain stable and allow isolation or trapping, in order to be used in other reactions. This review summarises the photochemical transformations of tetrazole derivatives that can be used as effective synthetic routes to other compounds.

References

Apr 29, 1998·Journal of Cardiovascular Pharmacology·Y HashimotoS Murata
Nov 28, 2001·The Journal of Organic Chemistry·Z P Demko, K B Sharpless
Jul 13, 2006·The Journal of Physical Chemistry. a·A Gómez-ZavagliaR Fausto
Mar 29, 2007·The Journal of Physical Chemistry. a·Luís M T FrijaR Fausto
Nov 2, 2007·Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology·L M T FrijaR Fausto
Mar 11, 2008·Organic & Biomolecular Chemistry·L M T FrijaM L S Cristiano

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Citations

Aug 16, 2011·Chemical Reviews·Haixiang Gao, Jean'ne M Shreeve
Jul 14, 2011·Organic & Biomolecular Chemistry·Luís M T FrijaM Lurdes S Cristiano
Jan 23, 2016·The Journal of Organic Chemistry·Hashim Fakhruddin MotiwalaJeffrey Aubé
Dec 2, 2014·The Journal of Organic Chemistry·A IsmaelM L S Cristiano
Sep 18, 2012·Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology·Amin IsmaelM Lurdes S Cristiano
Nov 5, 2016·The Journal of Organic Chemistry·A IsmaelM L S Cristiano
Feb 13, 2018·RSC Advances·Ajay L ChandgudeAlexander Dömling
Jul 13, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Chao-Wan ChangShie-Ming Peng
Nov 2, 2019·Angewandte Chemie·Nathaniel CorriganCyrille Boyer
Jul 23, 2020·Acta Crystallographica. Section E, Crystallographic Communications·Rizvan K AskerovA V Borisov
Nov 15, 2016·Green Chemistry : an International Journal and Green Chemistry Resource : GC·Ajay L Chandgude, Alexander Dömling
Jun 3, 2021·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Alina SecrieruMaria L S Cristiano
Feb 25, 2017·Chemical Reviews·Curt Wentrup
Feb 2, 2019·Chemical Reviews·Constantinos G NeochoritisAlexander Dömling

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Methods Mentioned

BETA
NMR

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