Photoelectrochemical cell for P-H/C-H cross-coupling with hydrogen evolution

Chemical Communications : Chem Comm
Jing-Hao WangLi-Zhu Wu

Abstract

Photoelectrochemistry enables the formation of a variety of active intermediates for organic synthesis in an environmentally friendly manner. Herein, a photoelectrochemical cell is fabricated to realize activation of P-H/C-H bonds for cross-coupling hydrogen evolution. As compared with an electrochemical cell, nearly 90% external bias input is saved to drive the C-P bond construction with good to excellent yields.

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Citations

Dec 26, 2019·Chemistry : a European Journal·Youai QiuLutz Ackermann
Dec 6, 2019·Angewandte Chemie·Joshua P Barham, Burkhard König
Mar 4, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Pengyan LiDongpeng Yan

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Methods Mentioned

BETA
cyclic voltammetry

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