Photoinduced isomerization-driven structural transformation between decanuclear and octadecanuclear gold(I) sulfido clusters

Journal of the American Chemical Society
Liao-Yuan Yao, Vivian Wing-Wah Yam

Abstract

Upon photoirradiation, isomerization of the ligands, 1,2-bis(diphenylphosphino)ethene (dppee) from the cis to the trans form in polynuclear gold(I) sulfido clusters, led to the structural transformation of the decagold(I) cluster to the octadecagold(I) cluster. Both polynuclear μ3-sulfido gold(I) clusters have been fully characterized by NMR, mass spectrometry, elemental analysis, and single crystal X-ray diffraction analysis. The transformation process could be readily detected and monitored by UV-vis absorption, emission, and (31)P NMR spectroscopy in solution. Supported and driven by Au(I)···Au(I) bonding interactions, the nuclearity and symmetry of these clusters were largely different from each other, resulting in completely distinct photophysical features.

References

Aug 10, 2000·Angewandte Chemie·D FenskeP Weis
May 8, 1997·Chemical Reviews·M. Concepción Gimeno, Antonio Laguna
May 8, 1997·Chemical Reviews·Pekka Pyykkö
Mar 6, 2003·Journal of the American Chemical Society·Masayuki NiheiHiroshi Nishihara
Jun 26, 2003·Journal of the American Chemical Society·Young-A Lee, Richard Eisenberg
Jul 10, 2003·Chemical Reviews·Christophe Dugave, Luc Demange
Aug 5, 2004·Journal of the American Chemical Society·Quan-Ming WangRichard Eisenberg
Jan 6, 2005·Journal of the American Chemical Society·Akihiro KishimuraTakuzo Aida
Mar 17, 2005·Chemical Communications : Chem Comm·Jinhua ChenMitchell R M Bruce
Dec 22, 2005·Journal of the American Chemical Society·Shu-Yan YuRongben Zhang
Apr 23, 2008·Angewandte Chemie·Shu-Yan YuVivian Wing-Wah Yam
Sep 3, 2008·Chemical Society Reviews·Vivian Wing-Wah Yam, Eddie Chung-Chin Cheng
Sep 3, 2008·Chemical Society Reviews·Hubert Schmidbaur, Annette Schier
Sep 3, 2008·Chemical Society Reviews·M Concepción Gimeno, Antonio Laguna
Sep 3, 2008·Chemical Society Reviews·Pekka Pyykkö
Sep 3, 2008·Chemical Society Reviews·R J Puddephatt
Nov 11, 2008·Chemical Communications : Chem Comm·Qing-Fu SunVivian Wing-Wah Yam
Nov 19, 2009·Journal of the American Chemical Society·Jian-Hua Jia, Quan-Ming Wang
Dec 3, 2010·Journal of the American Chemical Society·Terence Kwok-Ming LeeVivian Wing-Wah Yam
Feb 22, 2011·ACS Nano·Johannes MielkeLeonhard Grill
Apr 8, 2011·Chemical Communications : Chem Comm·Igor O KoshevoyTapani A Pakkanen
Aug 25, 2011·Chemical Society Reviews·Hubert Schmidbaur, Annette Schier
Mar 3, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Suresh BhargavaNedaossadat Mirzadeh
Feb 2, 2013·Journal of the American Chemical Society·Cornelius GahlMartin Weinelt
Apr 26, 2013·Chemical Reviews·Wiktor SzymańskiBen L Feringa
Jan 1, 2014·Chemistry : a European Journal·Terence Kwok-Ming LeeVivian Wing-Wah Yam
Dec 1, 2000·Angewandte Chemie·Vivian W-W Yam, Eddie C-C Cheng

❮ Previous
Next ❯

Citations

Jun 2, 2016·Journal of the American Chemical Society·Liao-Yuan YaoVivian Wing-Wah Yam
Feb 29, 2020·Chemical Communications : Chem Comm·Xu-Ran ChenJian-Ping Lang
Jul 14, 2018·Acta Crystallographica. Section E, Crystallographic Communications·Jimmy MugemanaShannon M Biros
Jun 2, 2017·Proceedings of the National Academy of Sciences of the United States of America·Stephanie M CraigMark A Johnson
Feb 2, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Julia R ShakirovaSergey P Tunik
Mar 1, 2016·Chemical Science·Christopher S WoodJonathan R Nitschke
Apr 30, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Aleksandra V PaderinaElena V Grachova
Sep 28, 2017·Journal of the American Chemical Society·Alexander M PolgarJohn F Corrigan
Jun 23, 2020·Journal of the American Chemical Society·Liang-Liang YanVivian Wing-Wah Yam
Oct 27, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Christopher M SatoJoseph P Sadighi

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.