Photolithographic Encoding of Metal Complexes

Chemistry : a European Journal
Christiane LangChristopher Barner-Kowollik

Abstract

A platform technology for the creation of spatially resolved surfaces encoded with a monolayer consisting of different metal complexes was developed. The concept entails the light-triggered activation of a self- assembled monolayer (SAM) of UV-labile anchors, that is, phenacylsulfides, and the subsequent cycloaddition of selected diene-functionalized metal complexes at defined areas on the surface. The synthesis and characterization of the metal complexes for the UV-light assisted anchoring on the surface and a detailed study of a short-chain oligomer model system in solution confirm the high efficiency of the photoreaction. The hybrid materials obtained by this concept can potentially be utilized for the design of highly valuable catalytic or (opto-)electronic devices.

References

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Dec 12, 2012·Chemical Communications : Chem Comm·Mathias GlassnerChristopher Barner-Kowollik
Jul 31, 2013·Angewandte Chemie·Thomas PauloehrlChristopher Barner-Kowollik
Sep 4, 2013·Advanced Materials·Cesar Rodriguez-EmmeneggerChristopher Barner-Kowollik
Apr 8, 2014·Macromolecular Rapid Communications·Thomas TischerChristopher Barner-Kowollik
Jun 17, 2014·ACS Applied Materials & Interfaces·Samuel J AdamsZoe Pikramenou
Feb 24, 2015·Langmuir : the ACS Journal of Surfaces and Colloids·Keita FuchiseChristopher Barner-Kowollik
Mar 19, 2015·Angewandte Chemie·Ozcan AltintasChristopher Barner-Kowollik

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Citations

Apr 14, 2017·Angewandte Chemie·Markus M ZiegerChristopher Barner-Kowollik
Oct 26, 2018·Chemistry : a European Journal·Rouven MüllerChristopher Barner-Kowollik
Apr 12, 2016·Chemistry : a European Journal·Sebastian BestgenPeter W Roesky

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