Photothermally reprogrammable buckling of nanocomposite gel sheets

Angewandte Chemie
Adam W HauserRyan C Hayward

Abstract

Patterning deformation within the plane of thin elastic sheets represents a powerful tool for the definition of complex and stimuli-responsive 3D buckled shapes. Previous experimental methods, however, have focused on sheets that access a limited number of shapes pre-programmed into the sheet, restricting the degree of dynamic control. Here, we demonstrate on-demand reconfigurable buckling of poly(N-isopropylacrylamide-co-acrylic acid) (PNIPAM) hydrogel network films containing gold nanoparticles (AuNPs) by patterned photothermal deswelling. Predictable, easily controllable, and reversible transformations from a single flat gel sheet to numerous different three-dimensional forms are shown. Importantly, the response time is limited by poroelastic mass transport, rather than photochemical switching kinetics, enabling reconfiguration of shape on timescales of several seconds, with further increases in speed possible by reducing film thickness.

References

Jul 6, 2000·Journal of Biomedical Materials Research·S R SershenJ L West
Apr 27, 2004·Nature Materials·Miguel Camacho-LopezMichael Shelley
Oct 29, 2005·The Journal of Chemical Physics·Chung-Yuen Hui, Vijayanand Muralidharan
May 18, 2006·Journal of the American Chemical Society·Nanfeng ZhengGalen D Stucky
Feb 27, 2007·Science·Yael KleinEran Sharon
Apr 3, 2007·Angewandte Chemie·Kazuki MatsubaraYukikazu Takeoka
Dec 28, 2010·Colloids and Surfaces. B, Biointerfaces·Eleonora MarsichSergio Paoletti
Nov 9, 2011·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·M A DiasC D Santangelo
Mar 10, 2012·Science·Jungwook KimRyan C Hayward
Mar 29, 2012·ACS Nano·Zhichen ZhuSvetlana A Sukhishvili
Apr 27, 2012·Advanced Materials·Kyung Min LeeTimothy J White
Mar 8, 2013·Journal of the American Chemical Society·Héloïse Thérien-AubinEugenia Kumacheva
May 8, 2013·Nano Letters·Eddie WangSeung-Wuk Lee
Aug 3, 2013·Nature Communications·Etienne PalleauOrlin D Velev
Jan 2, 2014·Langmuir : the ACS Journal of Surfaces and Colloids·Beatriz Martín-García, M Mercedes Velázquez
Jun 3, 2014·Nano Letters·Aoune BarhoumiDaniel S Kohane
Jul 17, 2014·Langmuir : the ACS Journal of Surfaces and Colloids·Vanessa RullaudPatrick Shahgaldian
Sep 19, 2007·Soft Matter·Christopher J BarrettTomiki Ikeda

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Citations

Oct 27, 2015·ACS Applied Materials & Interfaces·Molla R IslamMichael J Serpe
Feb 10, 2017·Accounts of Chemical Research·Seog-Jin JeonRyan C Hayward
Feb 22, 2017·Advanced Materials·Seog-Jin Jeon, Ryan C Hayward
Mar 4, 2017·Soft Matter·Sander KommerenC W M Bastiaansen
May 31, 2017·Angewandte Chemie·Adebola Oyefusi, Jian Chen
Jul 6, 2017·ACS Applied Materials & Interfaces·Zhao ZhengYiyun Cheng
Sep 22, 2018·Chemistry, an Asian Journal·Chen Yu LiQiang Zheng
Apr 24, 2019·Advanced Materials·Alexa S KuenstlerRyan C Hayward
Mar 30, 2019·Chemistry, an Asian Journal·Huanqing CuiXuemin Du
May 14, 2019·Advanced Materials·Hyunki KimRyan C Hayward
May 28, 2019·Scientific Reports·Tae Hyeob KimSeon Jeong Kim
Mar 17, 2020·Advanced Materials·Alexa S KuenstlerRyan C Hayward
Sep 10, 2020·Soft Matter·Pawan KumarÁgota Tóth
Jul 4, 2020·Bioinspiration & Biomimetics·Oliver SilverbergIsmail Emre Araci
Oct 20, 2017·Journal of Materials Chemistry. B, Materials for Biology and Medicine·Hongyu GuoZhihong Nie
Apr 8, 2020·Journal of Materials Chemistry. B, Materials for Biology and Medicine·Hongyu GuoZhihong Nie
May 26, 2016·Micromachines·Daniel MoralesOrlin D Velev
Jul 21, 2020·Advanced Functional Materials·Amanda EklundOlli Ikkala
Apr 25, 2019·Science Advances·Wenxin FanZhihong Nie
Apr 8, 2020·Journal of Materials Chemistry. B, Materials for Biology and Medicine·Zhi Jian WangQiang Zheng
Mar 30, 2020·Nature Chemistry·Florence G DownsHagan Bayley
Oct 27, 2018·Physical Review Letters·Adam W HauserRyan C Hayward
Mar 21, 2018·Journal of Materials Chemistry. B, Materials for Biology and Medicine·Guanghui YangJiaoning Tang
Jul 21, 2016·Advanced Materials·Dong-Dong HanHong-Bo Sun
Dec 29, 2020·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Pawan KumarDezső Horváth
Apr 13, 2021·Langmuir : the ACS Journal of Surfaces and Colloids·Yao Xiong, Olga Kuksenok
Jan 7, 2020·ACS Applied Materials & Interfaces·Wenxin FanKunyan Sui
Oct 31, 2019·ACS Applied Materials & Interfaces·Chen Fei DaiQiang Zheng
Jan 30, 2019·ACS Applied Materials & Interfaces·Jiayu LiuDavid H Gracias

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