Plasmon-induced charge separation: chemistry and wide applications

Chemical Science
Tetsu TatsumaTakuya Ishida

Abstract

Recent development of nanoplasmonics has stimulated chemists to utilize plasmonic nanomaterials for efficient and distinctive photochemical applications, and physicists to boldly go inside the "wet" chemistry world. The discovery of plasmon-induced charge separation (PICS) has even accelerated these trends. On the other hand, some confusion is found in discussions about PICS. In this perspective, we focus on differences between PICS and some other phenomena such as co-catalysis effect and plasmonic nanoantenna effect. In addition, materials and nanostructures suitable for PICS are shown, and characteristics and features unique to PICS are documented. Although it is well known that PICS has been applied to photovoltaics and photocatalysis, here light is shed on other applications that take better advantage of PICS, such as chemical sensing and biosensing, various photochromisms, photoswitchable functionalities and nanoscale photofabrication.

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Citations

Nov 15, 2017·Chemical Communications : Chem Comm·Seung Hyuk LeeTetsu Tatsuma
Nov 22, 2017·Physical Chemistry Chemical Physics : PCCP·Kun-Che KaoTetsu Tatsuma
Oct 3, 2018·Chemical Communications : Chem Comm·Hiroyasu NishiTetsu Tatsuma
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Aug 4, 2020·Physical Chemistry Chemical Physics : PCCP·Ambrose A MelvinAlexander Kuhn
Jan 19, 2018·Physical Chemistry Chemical Physics : PCCP·Kun-Che KaoTetsu Tatsuma
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Jul 3, 2019·Journal of the American Chemical Society·Mingrui YangMikhail Zamkov
Jan 16, 2020·ACS Applied Materials & Interfaces·Jiarui WuYichun Liu
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Methods Mentioned

BETA
surface plasmon resonance
biosensors
biosensing
atomic force microscopy

Software Mentioned

PICS

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