Platinum(II) N-heterocyclic carbene complexes: coordination and cyclometallation

Dalton Transactions : an International Journal of Inorganic Chemistry
Giacomo L PetrettoJonathan P Rourke

Abstract

Four different NHC ligands have been coordinated to Pt(II) centres; for the first time cyclometallation of the NHC ligand was observed, but only when the platinum centre had a DMSO and two methyl co-ligands. Cyclometallation resulted in the exclusive formation of five-membered rings, and the absence of any double cyclometallation reactions with appropriate ligands rules out the possibility of an oxidative addition type mechanism for the cyclometallation reaction.

References

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Citations

Aug 2, 2012·Acta Crystallographica. Section C, Crystal Structure Communications·Mario TenneThomas Strassner
May 25, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Dustin M JenkinsStefan Bernhard
Sep 19, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Paul MarshallAthanasia Dervisi
Feb 8, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Daniel Canseco-Gonzalez, Martin Albrecht
Mar 28, 2018·Chemistry : a European Journal·Johannes Soellner, Thomas Strassner
Sep 8, 2011·Angewandte Chemie·Ralte LalrempuiaMartin Albrecht
Oct 10, 2019·Chemistry : a European Journal·Piermaria PinterThomas Strassner
Sep 15, 2018·Chemistry : a European Journal·Johannes Soellner, Thomas Strassner
Dec 6, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Vsevolod KhlebnikovMartin Albrecht
Dec 21, 2016·Accounts of Chemical Research·Thomas Strassner

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