Poly( N-isopropylacrylamide- co-1-vinyl-3-alkylimidazolium bromide) Microgels with Internal Nanophase-Separated Structures

Langmuir : the ACS Journal of Surfaces and Colloids
Qingwen WuBinyang Du

Abstract

Microgels with internal nanophase-separated structures were fabricated by surfactant-free emulsion copolymerization of N-isopropylacrylamide (NIPAm) and ionic liquid comonomers, namely, 1-vinyl-3-alkylimidazolium bromide (VIM nBr) with various lengths n of long alkyl side chain, in an aqueous solution at 70 °C using N, N'-methylenebisacrylamide as the cross-linker. Combined techniques of transmission electron microscopy, dynamic and static light-scattering, differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), small-angle X-ray scattering (SAXS), and polarized optical microscopy were employed to systematically investigate the sizes, morphologies, and properties of the obtained microgels as well as the microstructures and phase transition of nanophases inside the microgels. The obtained P(NIPAm/VIM nBr) microgels are spherical with narrow size distributions, and the nanophases have a radius of about 8-12 nm and are randomly distributed inside the microgels. The cooperative competition of the hydrophilic quaternary vinylimidazole moieties and hydrophobic long alkyl side chains determines the thermal sensitive behavior of the P(NIPAm/VIM nBr) microgels. DSC and WAXD results reveal that the nanophases consis...Continue Reading

References

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