Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: photophysical and structural properties

Chemical Communications : Chem Comm
Juan-Manuel HerreraStephen Faulkner

Abstract

The complexes [Ru(CN)4(HAT)]2-, [{Ru(CN)4}2(mu2-HAT)]4- and [{Ru(CN)4}3(mu3-HAT)]6- (HAT = hexaaza-triphenylene) contain four, eight and twelve externally-directed cyanide ligands, respectively; they show strongly solvatochromic and intense MLCT absorptions, and [3]6- forms a high-dimensionality cyanide-bridged coordination network with Nd(III), in which Ru --> Nd energy transfer results in sensitised near-IR luminescence.

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Citations

Dec 13, 2006·Dalton Transactions : an International Journal of Inorganic Chemistry·Sofia DerossiMichael D Ward
Jan 25, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Theodore LazaridesMichael D Ward
Nov 9, 2017·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Szymon ChorazyBarbara Sieklucka
Nov 2, 2007·Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology·Theodore LazaridesMichael D Ward
Jul 10, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Michael D Ward
Apr 4, 2007·Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology·Margit KovácsAttila Horváth
Oct 12, 2013·Chemistry : a European Journal·Hua FengChi-Chiu Ko
Jan 27, 2019·Chemical Communications : Chem Comm·Szymon ChorazyBarbara Sieklucka
Jul 20, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Jennifer E JonesSimon J A Pope
Aug 24, 2007·Journal of the American Chemical Society·Juan-Manuel HerreraMichael D Ward

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