Porosity in metal-organic framework glasses

Chemical Communications : Chem Comm
A W ThorntonThomas D Bennett

Abstract

The porosity of a glass formed by melt-quenching a metal-organic framework, has been characterized by positron annihilation lifetime spectroscopy. The results reveal porosity intermediate between the related open and dense crystalline frameworks ZIF-4 and ZIF-zni. A structural model for the glass was constructed using an amorphous polymerization algorithm, providing additional insight into the gas-inaccessible nature of porosity and the possible applications of hybrid glasses.

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Citations

Aug 20, 2016·Journal of the American Chemical Society·Yingbo ZhaoC Austen Angell
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