Porous metal-organic framework based on mu4-oxo tetrazinc clusters: sorption and guest-dependent luminescent properties

Inorganic Chemistry
Lei HouXiao-Ming Chen

Abstract

A three-dimensional, highly porous metal-organic framework [Zn 4O(bdc)(bpz) 2].4DMF.6H 2O ( 1) (bdc = 1,4-benzenedicarboxylate, bpz = 3,3',5,5'-tetramethyl-4,4'-bipyrazolate) constructed by Zn 4O clusters with bdc and bpz linkers, has been prepared and structurally characterized. The N 2 sorption measurements reveal that 1 exhibits high porosity with a Langmuir surface area of 1908 m (2)/g and a pore volume of 0.58 cm (3)/g. Compound 1 features hydrophobic channels with a free passage of approximately 8.2 A defined by the methyl groups from bpz, and it exhibits nice sorption capability for benzene and toluene and interesting two-step sorption behavior for methanol. Meanwhile, 1 also exhibits interesting guest-dependent luminescent properties.

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Citations

Jun 22, 2011·Chemical Reviews·Yuanjing CuiBanglin Chen
Sep 24, 2011·Chemical Reviews·Jie-Peng ZhangXiao-Ming Chen
Mar 26, 2011·Chemical Communications : Chem Comm·Shui-Sheng ChenWei-Yin Sun
Oct 28, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Min-Le HanJun Zhao
Jan 1, 2009·Sensors·Marc N FiddlerSolomon Bililign
Oct 28, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Ruibiao FuXintao Wu
Dec 19, 2009·Chemistry : a European Journal·Claudio PettinariDaniela Pucci
Jun 12, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Yan-Qiong SunYi-Ping Chen
Feb 19, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Shui-Sheng ChenWei-Yin Sun
Aug 13, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Shyam BiswasDirk Volkmer
Nov 8, 2016·Advanced Science·Rui-Biao LinJie-Peng Zhang
Oct 27, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Chengfeng ZhuYong Cui
Jan 10, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Lei HouQi-Zhen Shi
Sep 11, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Saskia MenzelChristoph Janiak
Mar 11, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Malcolm A Halcrow
Nov 5, 2011·Chemistry : a European Journal·Lin-Hua Xie, Myunghyun Paik Suh
Nov 7, 2009·Journal of the American Chemical Society·JianJun ZhangMichael J Zaworotko
May 2, 2009·Inorganic Chemistry·Ming XueBanglin Chen
May 12, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Chris S Hawes
Oct 20, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Anjaiah Nalaparaju, Jianwen Jiang

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