Porous MOF with Highly Efficient Selectivity and Chemical Conversion for CO2

ACS Applied Materials & Interfaces
Hai-Hua WangZhonghua Zhu

Abstract

A new Co(II)-based MOF, {[Co2(tzpa)(OH)(H2O)2]·DMF}n (1) (H3tzpa = 5-(4-(tetrazol-5-yl)phenyl)isophthalic acid), was constructed by employing a tetrazolyl-carboxyl ligand H3tzpa. 1 possesses 1D tubular channels that are decorated by μ3-OH groups, uncoordinated carboxylate O atoms, and open metal centers generated by the removal of coordinated water molecules, leading to high CO2 adsorption capacity and significantly selective capture for CO2 over CH4 and CO in the temperature range of 298-333 K. Moreover, 1 shows the chemical stability in acidic and basic aqueous solutions. Grand canonical Monte Carlo simulations identified multiple CO2-philic sites in 1. In addition, the activated 1 as the heterogeneous Lewis and Brønsted acid bifunctional catalyst facilitates the chemical fixation of CO2 coupling with epoxides into cyclic carbonates under ambient conditions.

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Citations

Jun 7, 2018·Advanced Materials·Wenguang TuRong Xu
May 14, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Shan ChengYao-Yu Wang
Apr 30, 2019·Chemical Society Reviews·Meili DingOmar M Yaghi
Oct 9, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Hongmei WangLei Li
Jan 7, 2020·Topics in Current Chemistry·Ying ShiBin Zhao
Aug 23, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Hong-Yun YangZhonghua Zhu
Jan 31, 2018·Chemical Communications : Chem Comm·Yang YangZhong-Ming Sun
Sep 29, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhuxiu ZhangXu Qiao
Apr 3, 2020·Chemical Society Reviews·Ülkü Kökçam-DemirChristoph Janiak
Apr 15, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Rui ZhangWei Huang
Feb 12, 2021·ACS Applied Materials & Interfaces·Lu YangQinghua Xia
Apr 22, 2021·Chemical Communications : Chem Comm·Ning LiuJingqi Guan
May 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Shuai LiangHe-Gen Zheng
Jun 17, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiang-Jing Gao, He-Gen Zheng

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