Post-functionalization of a photoactive hybrid polyoxotungstate

Dalton Transactions : an International Journal of Inorganic Chemistry
Jamie M CameronHiroki Oshio

Abstract

A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalised derivatives of a phosphonate hybrid-POM are discussed, alongside a comparison of their electrochemical, photo-chemical and photo-oxidative properties.

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Citations

Dec 4, 2019·Chemical Society Reviews·Alexander V AnyushinTatjana N Parac-Vogt
Sep 16, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Aranya Kar, Chullikkattil P Pradeep
Nov 12, 2020·Chemical Communications : Chem Comm·Wenyan WangPaul Kögerler
Mar 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Thomas AuvrayEllen M Matson
Nov 13, 2020·Inorganic Chemistry·Ricarda PüttKirill Yu Monakhov

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