Precursor- and Time-Dependent Morphological Evolution of ZnO Nanostructures for Comparative Photocatalytic Activity and Adsorption Dynamics with Methylene Blue Dye

ACS Omega
Smriti Thakur, Sanjay K Mandal

Abstract

Diverse ZnO nanostructures were successfully fabricated at 700 °C by direct annealing of 1D Zn(II) coordination polymer precursors, namely, [Zn2(bpma)2(adc)2] n , [Zn2(bpea)2(adc)2] n , and {[Zn2(bpta)2(adc)2]·2H2O} n . The effect of sacrificial ligands present in the precursors as well as a variation in the retention time (6-24 h) during their synthesis resulted in 0D nanospheres, 1D microrods, and 3D polyhedra (with a diamond-like structure) of ZnO. The as-synthesized ZnO nanostructures were characterized by field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffractometry, diffuse reflectance spectroscopy, and Raman spectroscopy. The hexagonal crystal structure was confirmed for all the ZnO samples. A lattice spacing of 0.22 nm has been observed for nanospheres, whereas a lattice spacing of 0.26 nm has been observed for the polyhedra. Their Raman spectra confirm the wurtzite phase of ZnO. UV-vis spectra of ZnO nanostructures exhibit broad peaks in the range of 350-370 nm, and the band gap energies are found to be in the range of 3.02-3.20 eV. Based on the photoluminescence spectra photocatalytic activities of the as-synthesized ZnO nanostructures calcined for 12 h were tested with meth...Continue Reading

References

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Methods Mentioned

BETA
biosensors
X-ray
scanning electron microscopy
transmission electron microscopy
electron diffraction

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