PMID: 11924544Apr 2, 2002Paper

Predicting arsenic solubility in contaminated soils using isotopic dilution techniques

Environmental Science & Technology
Andrew M TyeK Kilham

Abstract

An isotopic dilution assay was developed to measure radiolabile As concentration in a diverse range of soils (pH 3.30-7.62; % C = 1.00-6.55). Soils amended with 50 mg of As kg(-1) (as Na2HAsO4 x 7H2O) were incubated for over 800 d in an aerated "microcosm" experiment. After 818 d, radiolabile As ranged from 27 to 57% of total applied As and showed a pH-dependent increase above pH 6. The radiolabile assay was also applied to three sets of soils historically contaminated with sewage sludge or mine-spoil. Results reflected the various geochemical forms in which the arsenic was present. On soils from a sewage disposal facility, radiolabile arsenate ranged from 3 to 60% of total As; mean lability was lower than in the equivalent pH range of the microcosm soils, suggesting occlusion of As into calcium phosphate compounds in the sludge-amended soils. In soils from mining areas in the U.K. and Malaysia, radiolabile As accounted for 0.44-19% of total As. The lowest levels of lability were associated with extremely large As concentrations, up to 17,000 mg kg(-1), from arsenopyrite. Soil pore water was extracted from the microcosm experiment and speciated using "GEOCHEM". The solid<==>solution equilibria of As in the microcosm soils was d...Continue Reading

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Citations

Nov 2, 2004·Analytical and Bioanalytical Chemistry·Annette L NolanMike J McLaughlin
Apr 21, 2011·Environmental Science & Technology·Jacqueline L StroudFang-Jie Zhao
Sep 23, 2010·The Science of the Total Environment·Stephanie Handley-SidhuDavid J Vaughan
Jun 27, 2008·Journal of Contaminant Hydrology·Shama HaqueKaren H Johannesson
Apr 7, 2012·Environmental Pollution·Jurate KumpieneMichel Mench
Feb 11, 2015·Environmental Monitoring and Assessment·Shirishkumar BaviskarChandan Mahanta
Jul 10, 2012·The Science of the Total Environment·M IzquierdoS R Chenery
Sep 12, 2016·The Science of the Total Environment·Michael SimmlerRuben Kretzschmar
Apr 13, 2004·Environmental Science & Technology·Rebecca E HamonMike J McLaughlin

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