Predicting Rearrangement-Competent Terpenoid Oxidation Levels.

Journal of the American Chemical Society
Christina H McCulley, Dean J Tantillo

Abstract

Results of density functional theory calculations on rearrangements of potential biosynthetic precursors to the sesquiterpenoid illisimonin A reveal that only some possible precursors, those with certain specific oxidation patterns, are rearrangement-competent.

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