Preparation of a tetraphenylethylene-based emitter: synthesis, structure and optoelectronic properties of tetrakis(pentaphenylphenyl)ethylene

Chemical Communications : Chem Comm
Vijay S Vyas, Rajendra Rathore

Abstract

Soluble tetrakis(pentaphenylphenyl)ethylene (1), prepared in three steps, allows non-emissive tetraphenylethylene (TPE) to turn into an emitter (Phi(F) = 0.13) owing to the steric bulk of the four large hexaphenylbenzene propellers which hamper =C-Ph and C=C bond rotations in the TPE core.

References

Jan 5, 2002·Chemical Reviews·Masahiro Irie
Apr 26, 2003·The Journal of Organic Chemistry·James E GanoEddie D Luzik
Jul 15, 2009·Chemical Communications : Chem Comm·Yuning HongBen Zhong Tang

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Citations

May 17, 2011·Chemical Communications : Chem Comm·Bin XuWenjing Tian
May 21, 2011·Chemical Communications : Chem Comm·Zujin ZhaoBen Zhong Tang
Mar 21, 2015·Scientific Reports·Yan ZhangJian-Guo Deng
Dec 31, 2016·Chemical Reviews·Saikat DasShilun Qiu
Feb 18, 2016·Chemical Society Reviews·Yan BaiHong-Cai Zhou
Jul 30, 2011·Chemical Society Reviews·Yuning HongBen Zhong Tang
Dec 13, 2012·Expert Opinion on Therapeutic Targets·Christopher D Goodman, Geoffrey I McFadden
Oct 7, 2018·Journal of Materials Chemistry. B, Materials for Biology and Medicine·Ting Ting KongBen Zhong Tang
Jun 24, 2017·Chemistry : a European Journal·Paramita DasPartha Sarathi Mukherjee
Aug 7, 2017·Journal of Polymer Science. Part A, Polymer Chemistry·C OrofinoP J Skabara
Dec 6, 2012·Chemical Communications : Chem Comm·Zhengfeng ChangBen Zhong Tang

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