Pressure-and temperature induced phase transitions, piezochromism, NLC behaviour and pressure controlled Jahn-Teller switching in a Cu-based framework.

Chemical Science
Charles J McMonagleStephen Moggach

Abstract

In situ single-crystal diffraction and spectroscopic techniques have been used to study a previously unreported Cu-framework bis[1-(4-pyridyl)butane-1,3-dione]copper(ii) (CuPyr-I). CuPyr-I was found to exhibit high-pressure and low-temperature phase transitions, piezochromism, negative linear compressibility, and a pressure induced Jahn-Teller switch, where the switching pressure was hydrostatic media dependent.

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Citations

Jul 20, 2021·Journal of Materials Chemistry. C, Materials for Optical and Electronic Devices·Rebecca ScatenaPiero Macchi

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Methods Mentioned

BETA
X-ray

Software Mentioned

PLATON

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