Probing Defects and Correlations in the Hydrogen-Bond Network of ab Initio Water

Journal of Chemical Theory and Computation
Piero GasparottoMichele Ceriotti

Abstract

The hydrogen-bond network of water is characterized by the presence of coordination defects relative to the ideal tetrahedral network of ice, whose fluctuations determine the static and time-dependent properties of the liquid. Because of topological constraints, such defects do not come alone but are highly correlated coming in a plethora of different pairs. Here we discuss in detail such correlations in the case of ab initio water models and show that they have interesting similarities to regular and defective solid phases of water. Although defect correlations involve deviations from idealized tetrahedrality, they can still be regarded as weaker hydrogen bonds that retain a high degree of directionality. We also investigate how the structure and population of coordination defects is affected by approximations to the interatomic potential, finding that, in most cases, the qualitative features of the hydrogen-bond network are remarkably robust.

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Citations

Apr 7, 2016·Chemical Reviews·Michele CeriottiThomas E Markland
May 21, 2016·The Journal of Physical Chemistry Letters·Bingqing ChengMichele Ceriotti
Jul 13, 2016·The Journal of Physical Chemistry. B·Francesco AmbrosioAlfredo Pasquarello
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Sep 10, 2021·Journal of the American Chemical Society·Rahul GeraAli A Hassanali

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