Probing Dynamic Library of Metal-Oxo Building Blocks with γ-Cyclodextrin

Journal of the American Chemical Society
Clément FalaiseEmmanuel Cadot

Abstract

Formation of one of the most representative polyoxometalate (POM) archetypes, namely the Lindqvist anion M6O192- with M = MoVI or WVI, was considered as elusive in aqueous solution. Herein, we report on the host-guest stabilization of the M6O192- species with M = Mo or W from aqueous solution using γ-cyclodextrin as trapping agent. The adduct {M6O19@γ-CD}2- reveals remarkable hydrolytic stability that offers new opportunities for exploring potentialities of molybdates or tungstates in the field of biology and medicine, when combined to CDs as efficient drug carrier/delivery agents.

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Citations

Jul 31, 2019·Chemical Communications : Chem Comm·Anton A IvanovEmmanuel Cadot
Jul 3, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Danjinkun LiuLixin Wu
Aug 20, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Lubin NiGreta R Patzke
Oct 10, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Anna A MukhachevaMaxim N Sokolov
Mar 13, 2020·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Khaleel I AssafWerner M Nau
Sep 30, 2020·Chemical Society Reviews·Nadiia I Gumerova, Annette Rompel
Jun 19, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Rong WanJingping Wang
May 7, 2019·Chemical Science·Maria Stuckart, Kirill Yu Monakhov
Dec 29, 2020·Journal of Colloid and Interface Science·Philipp SchmidPierre Bauduin
Aug 16, 2019·Journal of the American Society for Mass Spectrometry·Pei SuJulia Laskin
Jan 23, 2020·Inorganic Chemistry·Alexandra A ShmakovaMaxim N Sokolov
Sep 16, 2021·Chemistry : a European Journal·Ibrahima Fa BambaEmmanuel Cadot

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