Properties and toughening mechanisms of PVA/PAM double-network hydrogels prepared by freeze-thawing and anneal-swelling

Materials Science & Engineering. C, Materials for Biological Applications
Kangkang OuJinxin He

Abstract

It is well known that preparation method of hydrogels has a significant effect on their properties. In this paper, freeze-thawing and anneal-swelling were applied to prepare poly(vinyl alcohol)/polyacrylamide (PVA/PAM) double-network hydrogels with covalently and physically cross-linked networks. The properties of these hydrogels were investigated and compared to control hydrogels. Results indicated that hydrogels fabricated by freeze-thawing show larger pores size and higher swelling capacity than those made by anneal-swelling and control hydrogels. Hydrogels prepared by anneal-swelling exhibit higher mechanical strength, energy dissipation, fracture energy, gel fraction and crystallinity than those made by freeze-thawing and control hydrogels. Physical cross-linking plays a key role in formation of physical-chemical double-network. The toughening mechanism of double-network hydrogel is related to their chain-fracture behavior and elasticity. The results also indicated that appropriate methods can endow hydrogels with specific microstructures and properties which would broaden current hydrogels research and applications in biomedical fields.

Citations

Aug 3, 2019·Macromolecular Bioscience·Aurica P ChiriacVlad Mihai Chiriac
Jan 30, 2021·International Journal of Biological Macromolecules·Ling DingJi Zhang
Sep 4, 2021·Materials Science & Engineering. C, Materials for Biological Applications·Anuj Kumar, Sung Soo Han

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