Pyrrolidinium-based ionic liquids. 1-Butyl-1-methyl pyrrolidinium dicyanoamide: thermochemical measurement, mass spectrometry, and ab initio calculations

The Journal of Physical Chemistry. B
Vladimir N Emel'yanenkoRobert G Jones

Abstract

The standard molar enthalpy of formation of the ionic liquid 1-butyl-1-methylpyrrolidinium dicyanamide has been determined at 298 K by means of combustion calorimetry, while the enthalpy of vaporization and the mass spectrum of the vapor (ion pairs) have been determined by temperature-programmed desorption and line of sight mass spectrometry. Ab initio calculations for 1-butyl-1-methylpyrrolidinium dicyanamide have been performed using the G3MP2 and CBS-QB3 theory, and the results from homodesmic reactions are in excellent agreement with the experiments.

References

Feb 16, 2007·Physical Chemistry Chemical Physics : PCCP·James P ArmstrongIgnacio J Villar-Garcia

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Citations

Sep 24, 2009·Physical Chemistry Chemical Physics : PCCP·Alexey DeykoLeonid M Kustov
Feb 11, 2010·Physical Chemistry Chemical Physics : PCCP·Alasdair W TaylorRobert G Jones
Jun 11, 2010·Physical Chemistry Chemical Physics : PCCP·Kevin R J LovelockRobert G Jones
Oct 19, 2010·Physical Chemistry Chemical Physics : PCCP·Sergey P VerevkinMichael Frenkel
Jan 14, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Alasdair W TaylorPeter Licence
Aug 23, 2011·Physical Chemistry Chemical Physics : PCCP·A DeykoR G Jones
Mar 15, 2012·Physical Chemistry Chemical Physics : PCCP·Jing LiThomas Drewello
Oct 10, 2014·The Journal of Chemical Physics·Marisa A A RochaLuís M N B F Santos
Dec 11, 2014·Physical Chemistry Chemical Physics : PCCP·Miguel VilasLuís M N B F Santos
May 4, 2011·Chemistry : a European Journal·Ulrich PreissIngo Krossing
Jan 9, 2018·Royal Society Open Science·Kevin R J Lovelock
Oct 21, 2011·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Dzmitry H ZaitsauAndreas Heintz
Oct 12, 2018·The Journal of Chemical Physics·Fei WuClaudio J Margulis
Oct 10, 2013·Physical Chemistry Chemical Physics : PCCP·Kevin R J LovelockRobert G Jones
Feb 3, 2012·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Dzmitry H ZaitsauSergey P Verevkin
Jan 7, 2010·The Journal of Physical Chemistry. B·Steven D ChambreauStephen R Leone
Jun 27, 2009·The Journal of Physical Chemistry. B·Vladimir N Emel'yanenkoAxel Schulz
Apr 21, 2011·The Journal of Physical Chemistry Letters·Steven D ChambreauA A Viggiano
Mar 23, 2012·The Journal of Physical Chemistry. B·Sergey P VerevkinChristoph Schick
Dec 20, 2014·The Journal of Physical Chemistry. B·Changhui Xu, Claudio J Margulis
Nov 11, 2014·The Journal of Physical Chemistry. a·Steven D ChambreauStephen R Leone
Sep 8, 2011·The Journal of Physical Chemistry. B·Vladimir N Emel'yanenkoAxel Schulz
Oct 1, 2011·The Journal of Physical Chemistry. B·Sergey P VerevkinAndreas Heintz
Apr 1, 2015·The Journal of Physical Chemistry. B·Vitaly V Chaban, Iuliia V Voroshylova
Oct 26, 2018·The Journal of Physical Chemistry. B·Bingyu NieWei Zhang

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