Quantifying the Electrocatalytic Turnover of Vitamin B12-Mediated Dehalogenation on Single Soft Nanoparticles

Angewandte Chemie
Wei Cheng, Richard G Compton

Abstract

We report the electrocatalytic dehalogenation of trichloroethylene (TCE) by single soft nanoparticles in the form of Vitamin B12 -containing droplets. We quantify the turnover number of the catalytic reaction at the single soft nanoparticle level. The kinetic data shows that the binding of TCE with the electro-reduced vitamin in the Co(I) oxidation state is chemically reversible.

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Citations

Oct 19, 2016·Accounts of Chemical Research·Xianchan LiAndrew G Ewing
Dec 10, 2016·Angewandte Chemie·Eduardo LabordaRichard G Compton
Apr 30, 2017·Chemical Science·Ann FengRichard G Compton
Oct 7, 2016·Physical Chemistry Chemical Physics : PCCP·Peter H Robbs, Neil V Rees
Feb 12, 2019·Small·Wei XuXiaobo Ji
Mar 12, 2019·Angewandte Chemie·Mahmoud Elsayed HafezYi-Tao Long
Apr 25, 2019·Annual Review of Analytical Chemistry·Fato Tano PatriceYi-Tao Long
Mar 19, 2021·Inorganic Chemistry·Caroline K WilliamsJianbing Jimmy Jiang
Jul 2, 2019·Analytical Chemistry·Shashika Gunathilaka SabaragamuweJiyeon Kim

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