Quantitation of sulfate and thiosulfate in clinical samples by ion chromatography

Journal of Chromatography. a
D E Cole, J Evrovski

Abstract

For assay of serum sulfate, quantitation by ion conductimetry after separation by anion-exchange chromatography is the method of choice. In comparison to classical barium precipitation methods, chromatographic methods demonstrate increased precision, specificity and sensitivity, and they may be superior to spectrophotometric methods that rely on organic cation precipitation of sulfate. The increased sensitivity and specificity, as well as the inherent capacity of chromatographic methods for simultaneous determination of other anions, has led to its increasing use in the determination of excreted sulfate in clinical profiles of urinary anion composition. Ion chromatography can also be used to quantitate free sulfate in other clinical samples, including cerebrospinal fluid, sweat, saliva, breast milk and human tissues. Finally, ion chromatography shows promise as a more precise and sensitive method for measurement of total acid-labile sulfoesters and thiosulfate.

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Citations

Jun 1, 2013·Reproduction : the Official Journal of the Society for the Study of Fertility·Paul Anthony Dawson
Sep 27, 2008·Kidney International·Andreas PaschStefan Farese
Mar 23, 2011·Seminars in Cell & Developmental Biology·Paul A Dawson
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Sep 13, 2000·Critical Reviews in Clinical Laboratory Sciences·D E Cole, J Evrovski
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Mar 25, 2005·International Urology and Nephrology·Hippocrates Yatzidis
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Apr 2, 2005·American Journal of Physiology. Regulatory, Integrative and Comparative Physiology·Tsutomu NakadaShigehisa Hirose
Apr 20, 2018·Physiological Reports·Adrian PostStephan J L Bakker
Oct 21, 2020·Chembiochem : a European Journal of Chemical Biology·Aaron P LandryRuma Banerjee
Feb 13, 2009·Environmental Science & Technology·John F Oldi, Kurunthachalam Kannan
Oct 17, 2013·Analytical Chemistry·Adriana Nori de MacedoPhilip Britz-McKibbin

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