Radical-carbene coupling reaction: Mn-catalyzed synthesis of indoles from aromatic amines and diazo compounds

Chemical Communications : Chem Comm
Huihuang LiXiaobing Wan

Abstract

An unprecedented coupling reaction between aromatic amines and diazo compounds was well developed, which afforded a bridge connecting between radical chemistry and metal carbene chemistry. This Mn-catalyzed tandem reaction also provided a fundamentally different and practical approach to the indole skeleton under mild conditions.

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Citations

Oct 26, 2018·Chemistry : a European Journal·Shuya LiuYao Wang
Oct 16, 2019·Angewandte Chemie·Guojiao WuAxel Jacobi von Wangelin
Dec 20, 2018·Chemical Communications : Chem Comm·Bang LiuJin-Heng Li
May 6, 2021·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Federico Vittorio RossiEnrico Marcantoni

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