Raman spectroscopy for detection of ammonium nitrate as an explosive precursor used in improvised explosive devices

Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
Daniel Diaz, David W Hahn

Abstract

Raman spectroscopy was evaluated as a sensor for detection of ammonium nitrate (NH4NO3, AN), fuel oil (FO), AN-water solutions, and AN- and FO-soil mixtures deposited on materials such as glass, synthetic fabric, cardboard and electrical tape to simulate field conditions of explosives detection. AN is an inorganic oxidizing salt that is commonly used in fertilizers and mining explosives, however, due to its widespread accessibility, AN-based explosives are also utilized for the manufacture of improvised explosive devices (IED). Pure AN crystals were ground to powder size and deposited on several substrates for Raman analysis, whereas FO was analysed in a quartz cuvette. To simulate field conditions samples of powdered AN, AN-water solutions (0.1% to 10.0% AN w/w), AN-soil (50% to 90% AN w/w) and FO-soil (50% to 75% FO w/w) were prepared and deposited on the clutter materials. Raman spectra were acquired at integration times between 0.1 and 30 s, and 3 replicate Raman measurements were carried out for each sample. The spectral window observed ranged from 300 to 3800 cm-1. Several characteristic Raman bands were found, namely, at 710 cm-1 (NO3-) and 1040 cm-1 (NO3-) for AN; 1440-1470 cm-1 (CH) and 2800-3000 cm-1 (CH) for FO; 3000...Continue Reading

Citations

Mar 12, 2021·Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy·Sanchita SilSiva Umapathy

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