Rare-earth-metal nitridophosphates through high-pressure metathesis

Angewandte Chemie
Simon David Kloss, Wolfgang Schnick

Abstract

Developing a synthetic method to target an broad spectrum of unknown phases can lead to fascinating discoveries. The preparation of the first rare-earth-metal nitridophosphate LiNdP4 N8 is reported. High-pressure solid-state metathesis between LiPN2 and NdF3 was employed to yield a highly crystalline product. The in situ formed LiF is believed to act both as the thermodynamic driving force and as a flux to aiding single-crystal formation in dimensions suitable for crystal structure analysis. Magnetic properties stemming from Nd(3+) ions were measured by SQUID magnetometry. LiNdP4 N8 serves as a model system for the exploration of rare-earth-metal nitridophosphates that may even be expanded to transition metals. High-pressure metathesis enables the systematic study of these uncharted regions of nitride-based materials with unprecedented properties.

References

Aug 6, 2000·Acta Crystallographica. Section B, Structural Science·G BergerhoffT Degen
Jun 2, 2006·Angewandte Chemie·Friedrich Karau, Wolfgang Schnick
Aug 25, 2006·Nature·Michel Pouchard
Dec 6, 2006·The Journal of Chemical Physics·A MoiseJ J ter Meulen
Jun 15, 2007·Chemistry : a European Journal·Friedrich W KarauWolfgang Schnick
Apr 23, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·H-Jürgen Meyer
May 13, 2010·Chemistry : a European Journal·Florian J PucherWolfgang Schnick
Feb 28, 2014·Angewandte Chemie·Alexey MarchukWolfgang Schnick
Jul 19, 2014·Inorganic Chemistry·Dominik Baumann, Wolfgang Schnick
Aug 16, 2014·Angewandte Chemie·Dominik Baumann, Wolfgang Schnick
Jan 13, 2015·Angewandte Chemie·Alexey Marchuk, Wolfgang Schnick
Mar 15, 2015·Chemistry : a European Journal·Florian J PucherWolfgang Schnick

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Citations

Dec 16, 2016·Chemistry : a European Journal·Eva-Maria BertschlerWolfgang Schnick
Jan 30, 2018·Angewandte Chemie·Simon D KloßWolfgang Schnick
Jul 26, 2018·Chemistry : a European Journal·Mathias MallmannWolfgang Schnick
Jul 14, 2018·Chemistry : a European Journal·Sebastian Vogel, Wolfgang Schnick
Aug 24, 2018·Chemistry : a European Journal·Sebastian Wendl, Wolfgang Schnick
Nov 30, 2018·Angewandte Chemie·Simon D Kloß, Wolfgang Schnick
Jan 8, 2020·Chemistry : a European Journal·Mathias MallmannWolfgang Schnick
Feb 8, 2020·Chemistry : a European Journal·Sebastian WendlWolfgang Schnick
Nov 15, 2017·Chemistry : a European Journal·Eva-Maria BertschlerWolfgang Schnick
Oct 14, 2017·Chemistry : a European Journal·Eva-Maria BertschlerWolfgang Schnick
Jul 10, 2020·Angewandte Chemie·Sebastian WendlWolfgang Schnick
Nov 18, 2020·Angewandte Chemie·Sebastian WendlWolfgang Schnick
Mar 22, 2018·Inorganic Chemistry·Simon D Kloß, Wolfgang Schnick

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