Rational Design of MOF/COF Hybrid Materials for Photocatalytic H2 Evolution in the Presence of Sacrificial Electron Donors

Angewandte Chemie
Feng-Ming ZhangYa-Qian Lan

Abstract

Crystalline and porous covalent organic frameworks (COFs) and metal-organic frameworks (MOFs) materials have attracted enormous attention in the field of photocatalytic H2 evolution due to their long-range order structures, large surface areas, outstanding visible light absorbance, and tunable band gaps. In this work, we successfully integrated two-dimensional (2D) COF with stable MOF. By covalently anchoring NH2 -UiO-66 onto the surface of TpPa-1-COF, a new type of MOF/COF hybrid materials with high surface area, porous framework, and high crystallinity was synthesized. The resulting hierarchical porous hybrid materials show efficient photocatalytic H2 evolution under visible light irradiation. Especially, NH2 -UiO-66/TpPa-1-COF (4:6) exhibits the maximum photocatalytic H2 evolution rate of 23.41 mmol g-1  h-1 (with the TOF of 402.36 h-1 ), which is approximately 20 times higher than that of the parent TpPa-1-COF and the best performance photocatalyst for H2 evolution among various MOF- and COF-based photocatalysts.

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Citations

Feb 21, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Jia-Hui ZhaoKui Li
May 16, 2019·Angewandte Chemie·Luis Garzón-TovarDaniel Maspoch
Jul 31, 2019·Chemical Society Reviews·Liang FengHong-Cai Zhou
Mar 7, 2020·Chemistry : a European Journal·Huan PangYu Xia Xu
Aug 26, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Hong-Liang TangFeng-Ming Zhang
May 23, 2020·Advanced Science·Jie YinChun-Hua Yan
Feb 18, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhen HanZhongmin Su
Apr 12, 2021·Journal of Colloid and Interface Science·Yue ZhangYing-Hui Zhang
Apr 20, 2021·Journal of Materials Chemistry. B, Materials for Biology and Medicine·Xuan HuangJinjun Shao
Jun 19, 2021·ACS Applied Materials & Interfaces·Yongchao WangHongjian Yan
Jun 25, 2021·Chemical Science·Alexandre LegrandShuhei Furukawa

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