Reactions under autogenic pressure at elevated temperature (RAPET) of various alkoxides: formation of metals/metal oxides-carbon core-shell structures

Chemistry : a European Journal
Swati V PolA Gedanken

Abstract

The RAPET reaction at 700 degrees C, of different alkoxides (Ti, V, and Si) led to three different nanocomposites. Carbon is the element common to all three structures. Carbon was found as the core in the decomposition of TEOS, as the shell in the decomposition of VO(OEt)3 and embedded in, or mixed completely with, TiO2 in the decomposition of Ti(OiPr)4. This novel method using only metallic alkoxide precursor, in the absence of catalyst, leads in a one-step process to core-shell structures.

References

Sep 26, 2002·Chemical Communications : Chem Comm·Richard K BaldwinSusan M Kauzlarich
Aug 14, 2003·Journal of Nanoscience and Nanotechnology·M HirasawaN Aya

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Citations

Feb 27, 2016·Chemistry, an Asian Journal·Baohua LiFeiyu Kang
Jul 19, 2006·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Hiroaki TadaKoji Tanaka
Dec 11, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Qunling FangShouhu Xuan
Oct 7, 2011·Beilstein Journal of Nanotechnology·Michal EshedMahalingam Balasubramanian
Aug 15, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Hamid ChoujaaKieran C Molloy
Jun 8, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·J M ClarkA Sudlow
Jan 25, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Nathan HollingsworthSumpun Wongnawa
Jun 19, 2009·Inorganic Chemistry·Vilas G PolMonica Popa
Aug 9, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·Swati V PolAharon Gedanken
Sep 8, 2006·The Journal of Physical Chemistry. B·David S JacobAharon Gedanken
Jul 21, 2006·The Journal of Physical Chemistry. B·S V PolA Gedanken

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