Recent Advances in Catalytic Hydrosilylations: Developments beyond Traditional Platinum Catalysts.

Angewandte Chemie
Leandro Duarte de AlmeidaMatthias Beller

Abstract

Hydrosilylation reactions, which allow the addition of Si-H to C=C/C≡C bonds, are typically catalyzed by homogeneous noble metal catalysts (Pt, Rh, Ir, and Ru). Although excellent activity and selectivity can be obtained, the price, purification, and metal residues of these precious catalysts are problems in the silicone industry. Thus, a strong interest in more sustainable catalysts and for more economic processes exists. In this respect, recently disclosed hydrosilylations using catalysts based on earth-abundant transition metals, for example, Fe, Co, Ni, and Mn, and heterogeneous catalysts (supported nanoparticles and single-atom sites) are noteworthy. This minireview describes the recent advances in this field.

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Citations

Feb 5, 2021·Angewandte Chemie·Jie KeChuan He
Sep 19, 2021·Chemistry, an Asian Journal·Katsuaki Kobayashi, Hiroshi Nakazawa
Oct 12, 2021·Chemistry : a European Journal·Hanna StachowiakGrzegorz Hreczycho

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Methods Mentioned

BETA
transmission electron microscopy

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