Recent advances in low oxidation state aluminium chemistry.

Chemical Science
Katie HobsonClare Bakewell

Abstract

The synthesis and isolation of novel low oxidation state aluminium (Al) compounds has seen relatively slow progress over the 30 years since such species were first isolated. This is largely due to the significant challenges in isolating these thermodynamically unstable compounds. Despite challenges with isolation, their reactivity has been widely explored and they have been utilized in a wide range of processes including the activation of strong chemicals bonds, as ligands to transition metals and in the formation of heterobimetallic M-M compounds. As such, attempts to isolate novel low oxidation state Al compounds have continued in earnest and in the last few years huge advances have been made. In this review we highlight the remarkable recent developments in the low oxidation state chemistry of aluminium and discuss the variety of new reactions these compounds have made possible.

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Citations

Jun 25, 2021·Chemical Science·Maria BatuecasMark R Crimmin
Nov 11, 2020·Journal of the American Chemical Society·Kristian L MearsPhilip P Power
Aug 7, 2020·Chemistry : a European Journal·Catherine Weetman
Jun 3, 2021·Chemical Communications : Chem Comm·Weixing ChenXiao-Juan Yang
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May 13, 2021·Chemical Communications : Chem Comm·Adrian HauserPeter W Roesky
Aug 18, 2021·Chemistry : a European Journal·Ryan J SchwammNasir A Rajabi
Oct 27, 2021·Journal of the American Chemical Society·Kota Koshino, Rei Kinjo

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Methods Mentioned

BETA
X-ray
NMR
XRD

Software Mentioned

DFT

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