Recent advances in radical transformations of internal alkynes

Chemical Communications : Chem Comm
Min-Hua HuangBo Jiang

Abstract

Over the past years, impressive progress has been made on the development of the chemoselective and direct formation of carbon-carbon and carbon-heteroatom bonds involving internal alkynes under catalytic oxidative systems. These transformations heavily rely on the in situ generation of reactive radical intermediates that are initiated by oxidants, visible light photocatalysis, or electrocatalysis and so on. Numerous chemically and biomedically important building blocks have been synthesized, and will continue to be obtained by taking advantage of the radical transformation of internal alkynes in the following years. In this review, we highlight the recent progress in this rapidly growing area by presenting a series of catalytic oxidative reactions, mechanisms and applications which have appeared in the most recent literature.

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Citations

Oct 16, 2018·Organic & Biomolecular Chemistry·Bang ZhouYun Liang
Feb 27, 2019·Chemical Communications : Chem Comm·Xiao-Yan QinBo Jiang
Jul 3, 2019·Chemistry, an Asian Journal·Harekrishna SahooMahiuddin Baidya
Oct 28, 2019·Chemical Communications : Chem Comm·Yunhe LvMengxing Cui
Dec 19, 2019·Chemical Communications : Chem Comm·Jian LeiXiaolan Xie
Nov 30, 2019·Chemistry, an Asian Journal·Tian-Shu ZhangBo Jiang
Oct 23, 2020·Organic & Biomolecular Chemistry·José María Muñoz-MolinaPedro J Pérez
Dec 12, 2020·Organic & Biomolecular Chemistry·Praveen P Singh, Vishal Srivastava
Dec 23, 2020·Chemical Society Reviews·Rolando CannalireMariateresa Giustiniano
Jan 5, 2021·Chemical Communications : Chem Comm·Tonghao ZhuJie Wu
Mar 12, 2021·The Journal of Organic Chemistry·Haopeng WuFu-Xue Chen
Mar 10, 2020·Accounts of Chemical Research·Santosh K PagireOliver Reiser
Feb 23, 2019·The Journal of Organic Chemistry·Li ChengTuan-Jie Li
Jul 8, 2020·The Journal of Physical Chemistry Letters·Tao WangJunfa Zhu
Aug 29, 2020·Organic Letters·Tonghao Zhu, Jie Wu
Nov 9, 2019·The Journal of Organic Chemistry·Xiaoying HuangYanyan Chen

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Methods Mentioned

BETA
X-ray
ESR

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