Recent advances in the sulfonylation of alkenes with the insertion of sulfur dioxide via radical reactions

Chemical Communications : Chem Comm
Guanyinsheng QiuJie Wu

Abstract

Recent advances in the sulfonylation of alkenes via the insertion of sulfur dioxide are summarized. The sulfur dioxide surrogate of DABCO·(SO2)2 or inorganic sulfites is used in the transformation through a radical process. Two strategies for the sulfonylation of alkenes with the insertion of sulfur dioxide have been developed. In most cases, the vicinal difunctionalization of alkenes is initiated by the arylsulfonyl radical generated in situ. Although the sulfonylation of alkenes with the insertion of sulfur dioxide is efficient, the asymmetric versions are still challenging and less to be explored. It is expected that the asymmetric vicinal difunctionalization of alkenes with the insertion of sulfur dioxide will be developed rapidly in the near future.

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Citations

Oct 24, 2018·Chemical Communications : Chem Comm·Guanyinsheng QiuJie Wu
Jan 3, 2019·Chemical Communications : Chem Comm·Shengqing YeJie Wu
Feb 1, 2019·Chemical Communications : Chem Comm·Shengqing YeGuanyinsheng Qiu
Feb 27, 2019·Chemical Communications : Chem Comm·Xiao-Yan QinBo Jiang
Apr 14, 2019·Chemistry : a European Journal·Quan-Qing ZhaoWen-Jing Xiao
Nov 28, 2019·Chemical Communications : Chem Comm·Xuefeng WangJie Wu
Feb 20, 2020·Chemical Communications : Chem Comm·Jun ZhangJie Wu
Feb 27, 2020·Chemical Communications : Chem Comm·Xuefeng WangJie Wu
Apr 4, 2020·Chemical Communications : Chem Comm·Shengqing YeJie Wu
Aug 20, 2020·Chemical Communications : Chem Comm·Fu-Sheng HeJie Wu
Oct 22, 2020·Chemical Communications : Chem Comm·Chun ZhangJie Wu
Dec 12, 2020·Organic & Biomolecular Chemistry·Praveen P Singh, Vishal Srivastava
Jan 5, 2021·Chemical Communications : Chem Comm·Tonghao ZhuJie Wu
Jan 19, 2021·Organic & Biomolecular Chemistry·Jian YangJi-Yu Wang
Aug 14, 2020·Chemical Reviews·Stefano Crespi, Maurizio Fagnoni
Jun 12, 2021·Chemical Communications : Chem Comm·Yi-Lin LiuWen-Ting Wei
Jul 29, 2021·Chemical Communications : Chem Comm·Stephan P BlumSiegfried R Waldvogel
Jan 10, 2019·The Journal of Organic Chemistry·Priyanka HalderSantosh B Mhaske
Aug 29, 2020·Organic Letters·Tonghao Zhu, Jie Wu

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