PMID: 10203775Apr 17, 1999

Recent biotechnological developments in the use of peroxidases

Trends in Biotechnology
S ColonnaP Pasta

Abstract

Peroxidases are ubiquitous oxidoreductases that use hydrogen peroxide or alkyl peroxides as oxidants. Advances have recently been made in using them to prepare, under mild and controlled conditions, chiral organic molecules that are valuable for the chemoenzymatic synthesis of a wide range of useful compounds. Horseradish peroxidase can be converted into a peroxygenative enzyme by molecular engineering. Chloroperoxidase, the most versatile peroxidase, behaves like a 'true' monooxygenase in sulfoxidations with molecular oxygen and an external reductant, with substantial increases in enantioselectivity and enzyme stability.

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Related Concepts

Alcohols
Biotechnology
Catalysis
Enzyme Stability
Hydroxylation
Indoles
Nitrogen
Oxidation-Reduction
Ovoperoxidase
Sulfur

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