Recent developments in the chemistry of non-trigonal pnictogen pincer compounds: from bonding to catalysis.

Chemical Science
Josh Abbenseth, Jose M Goicoechea

Abstract

The combination of well-established meridionally coordinating, tridentate pincer ligands with group 15 elements affords geometrically constrained non-trigonal pnictogen pincer compounds. These species show remarkable activity in challenging element-hydrogen bond scission reactions, such as the activation of ammonia. The electronic structures of these compounds and the implications they have on their electrochemical properties and transition metal coordination are described. Furthermore, stoichiometric and catalytic bond forming reactions involving B-H, N-H and O-H bonds as well as carbon nucleophiles are presented.

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Citations

Jan 20, 2021·Journal of the American Chemical Society·Jeffrey M LipshultzAlexander T Radosevich
Dec 12, 2020·Journal of the American Chemical Society·Seung Jun HwangAlexander T Radosevich
Dec 22, 2020·Journal of the American Chemical Society·Priyabrata GhanaAlexander C Filippou
Aug 13, 2021·Angewandte Chemie·Joey FeldJose M Goicoechea
Sep 4, 2021·Angewandte Chemie·Josh AbbensethJose M Goicoechea
Sep 22, 2021·Chemistry : a European Journal·Jingjing CuiHolger Braunschweig

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Methods Mentioned

BETA
X-ray
NMR
isothermal titration calorimetry

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