Recent developments in the synthesis and utilization of chiral β-aminophosphine derivatives as catalysts or ligands

Chemical Society Reviews
Wenbo Li, Junliang Zhang

Abstract

In the last few years, the research area of chiral β-aminophosphines capable of promoting a wide range of diverse organic transformations has attracted more attention. Their derivatives constitute attractive reagents towards this end, due to their stability, low toxicity and ease of handling. These novel β-aminophosphine derivatives are potentially useful as organocatalysts and ligands in metal-catalysed reactions. In particular, chiral β-aminophosphines have recently emerged as powerful phosphine catalysts in asymmetric synthesis and catalysis. The asymmetric transformations to which metal complexes of these ligands have been applied include palladium-catalysed allylic substitutions and copper-catalysed 1,4-additions to enones among others. This review summarizes the most significant developments in the area of synthesis and application of chiral β-aminophosphine derivatives, providing a detailed overview of the current state of the art and including future aspects.

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Citations

Mar 23, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Erika BálintGyörgy Keglevich
May 27, 2016·Chemical Communications : Chem Comm·Wei ZhouJunliang Zhang
May 16, 2019·Organic & Biomolecular Chemistry·Jian-Qiang ZhaoWei-Cheng Yuan
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Jul 8, 2020·Chemical Communications : Chem Comm·Maizhan Li, Wei Zhou
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Jan 29, 2021·Chemical Communications : Chem Comm·Athukuri EdukondaluWenwei Lin
Jan 6, 2021·The Journal of Organic Chemistry·Jianning LiaoHongchao Guo
Dec 16, 2020·Chemical Communications : Chem Comm·Yifan HuangHongchao Guo
Jun 18, 2021·Organic & Biomolecular Chemistry·Xinzhi ZhangJun Jiang
Jun 18, 2021·Organic & Biomolecular Chemistry·Yangyang ZhangJun Jiang
Jun 15, 2021·Chemical Science·Erik C VikKen D Shimizu

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