Recent Progress of Transition Metal Phosphides for Photocatalytic Hydrogen Evolution.

ChemSusChem
Long-Fei HongWei-Guo Pan

Abstract

Photocatalytic hydrogen evolution can effectively alleviate the troublesome global energy crisis by converting solar energy into the chemical energy of hydrogen. In order to realize efficient hydrogen generation, a variety of semiconductor materials have been extensively investigated, including TiO2 , CdS, g-C3 N4 , metal-organic frameworks (MOFs), and others. In recent years, to achieve higher photocatalytic performance and reach the level of large-scale industrial applications, photocatalysts decorated with transition metal phosphides (TMPs) have shone brightly because of their low cost, stable physical and chemical properties, and substitution for precious metals of TMPs. This Review highlights the preparation methods and properties associated with photocatalysis of TMPs. Moreover, the H2 generation efficiency of photocatalysts loaded with TMPs and the roles of TMPs in catalytic systems are also studied systematically. Apart from being co-catalysts, several TMPs can also serve as host catalysts to boost the activity of photocatalytic composites. Finally, the development prospects and challenges of TMPs are put forward, which is valuable for future researchers to expand the application of TMPs in photocatalytic directions and...Continue Reading

References

Jun 19, 2013·Chemical Reviews·Sophie CarencoClément Sanchez
Jan 29, 2016·Scientific Reports·Huanqing ChengWen-Fu Fu
Jan 20, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Jiuqing WenGuican Bi
Aug 25, 2017·ACS Applied Materials & Interfaces·Zhichao SunTetsuro Majima
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Sep 10, 2019·Journal of Colloid and Interface Science·Zhiliang JinQingxiang Ma

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Citations

May 13, 2021·Nanoscale·Alexandra Mavridi-PrinteziMarco Montalti

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