Reductive cleavage of P4 by iron(I) centres: synthesis and structural characterisation of Fe2(P2)2 complexes with two bridging P2(2-) ligands

Chemical Communications : Chem Comm
Shenglai YaoMatthias Driess

Abstract

The selective transformation of white phosphorus with a β-diketiminato iron(I) toluene complex under mild reaction conditions is reported which furnishes a new dinuclear iron(III) Fe2(P2)2 complex with two bridging P2(2-) ligands. Its reduction with potassium results in the formation of the first delocalised mixed-valent bis-diphosphido iron(II,III) complex which is isostructural with the neutral Fe2P4 precursor.

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Dec 6, 2014·Angewandte Chemie·Shenglai YaoMatthias Driess

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Citations

Mar 1, 2016·Angewandte Chemie·Fabian SpitzerManfred Scheer
Sep 22, 2016·Chemistry : a European Journal·Stefan PeltiesRobert Wolf
Nov 4, 2016·Chemical Communications : Chem Comm·Christoph SchooPeter W Roesky
Dec 30, 2016·Chemistry : a European Journal·Fabian SpitzerManfred Scheer
Feb 24, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Uttam ChakrabortyRobert Wolf
Dec 16, 2017·Angewandte Chemie·Anthony CavailléNicolas Mézailles
Mar 19, 2019·Chemistry : a European Journal·Moritz ModlManfred Scheer
Jul 28, 2019·Angewandte Chemie·Munmun GhoshFranc Meyer
Sep 29, 2019·Angewandte Chemie·Anup K AdhikariRobert Wolf
Sep 15, 2017·Angewandte Chemie·Montaha H AnjassCarsten Streb
Aug 4, 2020·Zeitschrift für anorganische und allgemeine Chemie·Christoph G P ZieglerRobert Wolf
Oct 8, 2020·Chemical Communications : Chem Comm·Fabian SpitzerManfred Scheer
Apr 2, 2021·Journal of the American Chemical Society·Jingzhen DuStephen T Liddle
May 11, 2021·Chemistry : a European Journal·Veronika HeinlManfred Scheer
Mar 23, 2019·Chemical Reviews·Michael SeidlManfred Scheer
Nov 4, 2021·Chemistry : a European Journal·Maria HaimerlManfred Scheer

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