Regioselective opening of proximally sulfato-capped cyclodextrins

Chemical Communications : Chem Comm
Matthieu JouffroyLoïc Toupet

Abstract

Sulfato groups capping one or two pairs of adjacent glucose units in methylated cyclodextrin (CD) derivatives have been found to undergo regioselective opening with various nucleophiles; the reported methodology opens the way to the efficient synthesis of tridifferentiated α- and β-cyclodextrins that constitute key starting materials for the preparation of heteropolydentate cavitands.

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Mar 3, 2011·Chemistry : a European Journal·Rafael Gramage-DoriaLoïc Toupet

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Citations

Jun 24, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Matthieu JouffroyDominique Matt
Feb 26, 2019·Chemistry : a European Journal·Stella A VerkhnyatskayaMarthe T C Walvoort

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