Reliable method for determining the oxidation state in chromium oxides

Inorganic Chemistry
Angel M Arévalo-López, Miguel A Alario-Franco

Abstract

We show that an appropriate analysis of the electron energy loss spectra in relation to the Cr-O bonds gives a reliable methodology to obtain the oxidation state in chromium oxides. It is based on the energy difference between the Cr L(3) and O K edges, which acts as a measure of the binding energy difference between the Cr 2p(3/2) and O 1s core levels.

References

Apr 1, 1993·Physical Review. B, Condensed Matter·D H PearsonB Fultz
Jul 15, 1993·Physical Review. B, Condensed Matter·H Kurata, C Colliex
Apr 26, 2005·Inorganic Chemistry·Rocío Ruiz-BustosMiguel A Alario-Franco
Feb 16, 2006·Chemical Communications : Chem Comm·Andrey KarpovMartin Jansen
Nov 19, 2008·Angewandte Chemie·Martin Jansen, Ulrich Wedig
Dec 2, 2008·Angewandte Chemie·Samuel J MugaveroHans-Conrad zur Loye

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Citations

Apr 23, 2014·Microscopy and Microanalysis : the Official Journal of Microscopy Society of America, Microbeam Analysis Society, Microscopical Society of Canada·Lluís YedraFrancesca Peiró
Feb 24, 2016·Microscopy and Microanalysis : the Official Journal of Microscopy Society of America, Microbeam Analysis Society, Microscopical Society of Canada·Philip EwelsLuc Lajaunie
Dec 19, 2015·Advanced Materials·Tiffany C KasparScott A Chambers
Feb 17, 2010·Inorganic Chemistry·Angel M Arévalo-LópezMiguel A Alario-Franco
Feb 20, 2018·Langmuir : the ACS Journal of Surfaces and Colloids·Felix LampertPer Møller

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