Removal of aqueous Cr(VI) by Zn- and Al-modified hydrochar

Chemosphere
Feiyue LiBin Gao

Abstract

Pristine hydrochar is a carbonaceous material that can sorb hexavalent chromium (Cr(VI)), a kind of toxic pollutants and difficult to removal, from aqueous solution but its capacity is limited. With the goal of improving this ability, two modified hydrochars were produced by co-hydrothermal carbonization (200 °C, 7h) of bamboo sawdust with zinc chloride (ZnCl2) or aluminum chloride (AlCl3). Compared to the pristine hydrochar, the ZnCl2-and AlCl3-modified hydrochars were more fully carbonized (higher C content and lower H/C) and had higher surface area (increased by 26 and 4.3 times, respectively) and larger pore volume (increased by 43 and 5.5 times, respectively). Due to these improved properties, the Cr(VI) maximum adsorption capacity (modeled via Langmuir isotherms) of ZnCl2-and AlCl3-modified hydrochar increased by 3.4 and 2.8 times, respectively. In addition, Cr(VI) adsorption kinetic of modified hydrochar was well fitted by the pseudo-second-order model. Cr sorption capacity increased at low pH and ion strengths, suggesting the potential roles of electrostatic interaction and ion exchange mechanisms. These results indicate that hydrochars modified by ZnCl2 and AlCl3 treatment are promising in environmental applications th...Continue Reading

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.